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Please use this identifier to cite or link to this item: http://ri.uaemex.mx/handle20.500.11799/68580
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dc.contributor.authorJonathan Jaramillo Garciaen_EU
dc.contributor.authorVíctor Sánchez Mendietaen_EU
dc.contributor.authorIvan Garcia Orozcoen_EU
dc.contributor.authorRAUL ALBERTO MORALES LUCKIEen_EU
dc.contributor.authorDiego Martínez Oteroen_EU
dc.contributor.authorANTONIO TELLEZ LOPEZen_EU
dc.contributor.authorLuis D. Rosales-Vázquezen_EU
dc.contributor.authorRoberto Escudero Deraten_EU
dc.contributor.authorFrancisco Moralesen_EU
dc.creatorJonathan Jaramillo Garcia-
dc.creatorVíctor Sánchez Mendieta-
dc.creatorIvan Garcia Orozco-
dc.creatorRAUL ALBERTO MORALES LUCKIE-
dc.creatorDiego Martínez Otero-
dc.creatorANTONIO TELLEZ LOPEZ-
dc.creatorLuis D. Rosales-Vázquez-
dc.creatorRoberto Escudero Derat-
dc.creatorFrancisco Morales-
dc.date2018-01-18-
dc.date.accessioned2019-03-12T23:44:06Z-
dc.date.available2019-03-12T23:44:06Z-
dc.identifierhttp://hdl.handle.net/20.500.11799/68580-
dc.identifier.urihttp://ri.uaemex.mx/handle20.500.11799/68580-
dc.descriptionMuconato-bridged Manganese Coordination Polymer exhibiting rare Distorted-trigonal Prismatic Coordination Arrangement-
dc.descriptionNovel poly[Mn(H2O)(dmb)(muco)] (1) (H2muco = trans,trans-muconic acid; dmb = 5,5 -dimethyl-2,2 -bipyridine) was obtained by self-assembly, one-pot, solution reaction. 1 crystallizes in a monoclinic system with P21 space group and forms an infinite onedimensional (1D) polymer. Remarkably, the six-coordinate MnII display a rare distorted trigonal prismatic configuration. This unusual co-ordination arrangement appears to be acquired due to the supramolecular interactions of the polymeric structure of 1, mainly throughout hydrogen bonding, giving rise to a 2D framework. Magnetic properties measurements reveal that 1 possesses weak antiferromagnetic interactions with θ(C–W) = –1.0 K and J = 458 cm–1.-
dc.languageeng-
dc.publisherJournal of Inorganic and General Chemistry-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0-
dc.source1521-3749-
dc.subjectcoordination polyer-
dc.subjectmanganese-
dc.subjectmuconato-
dc.subjectmagnetism-
dc.subjectinfo:eu-repo/classification/cti/2-
dc.titleMuconato-bridged Mn coordination polymer exhibiting rare distorted-trigonal prismatic coordination geometry-
dc.typearticle-
dc.audiencestudents-
dc.audienceresearchers-
item.fulltextNo Fulltext-
item.grantfulltextnone-
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