Please use this identifier to cite or link to this item:
http://ri.uaemex.mx/handle20.500.11799/104783
DC Field | Value | Language |
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dc.creator | IVANN ZARAGOZA GALICIA | - |
dc.creator | ZAIRA ARGELIA SANTOS SANCHEZ | - |
dc.creator | Yazmín Itzel Hidalgo Mercado | - |
dc.creator | Horacio Olivo | - |
dc.creator | MOISES ROMERO ORTEGA | - |
dc.date | 2019-10-08 | - |
dc.date.accessioned | 2022-04-21T06:01:45Z | - |
dc.date.available | 2022-04-21T06:01:45Z | - |
dc.identifier | http://hdl.handle.net/20.500.11799/104783 | - |
dc.identifier.uri | http://ri.uaemex.mx/handle20.500.11799/104783 | - |
dc.description | En el presente trabajo se describe un procedimiento simple y fácil para la preparación de pirrolidinonas 5-sustituidas a partir de un acoplamiento entre iones N-aciliminio y reactivos organometálicos derivados de zinc | - |
dc.description | A coupling reaction between cyclic N-acyliminium ions with organozinc reagents is described. The cyclic N-acyliminium ions, generated in situ from N-substituted-5-hydroxy-2-pyrrolidinones by treatment with BF3-etherate or titanium tetrachloride, were trapped by the organozinc reagent, formed by the alkylbromide in the presence of zinc in the same reaction media. The N-substituted 5-allyl-2-pyrrolidinones generated using this method, serves as versatile intermediates for the synthesis of azabicyclic systems with indolizidine and pyrroloazepinolizidine cores. | - |
dc.language | eng | - |
dc.publisher | Thieme | - |
dc.rights | info:eu-repo/semantics/openAccess | - |
dc.rights | http://creativecommons.org/licenses/by-nc-nd/4.0 | - |
dc.source | 0039-7881 | - |
dc.subject | Synthesis of 5-Substituted-2-pyrrolidinones by coupling of organozinc reagents with cyclic N-acyliminium ions | - |
dc.subject | info:eu-repo/classification/cti/2 | - |
dc.title | Synthesis of 5-substituted 2-pyrrolidinones by coupling of organozinc reagents with cyclic N-acyliminium ions | - |
dc.type | article | - |
dc.audience | students | - |
dc.audience | researchers | - |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
Appears in Collections: | Producción |
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