Please use this identifier to cite or link to this item: http://ri.uaemex.mx/handle20.500.11799/104783
DC FieldValueLanguage
dc.creatorIVANN ZARAGOZA GALICIA-
dc.creatorZAIRA ARGELIA SANTOS SANCHEZ-
dc.creatorYazmín Itzel Hidalgo Mercado-
dc.creatorHoracio Olivo-
dc.creatorMOISES ROMERO ORTEGA-
dc.date2019-10-08-
dc.date.accessioned2022-04-21T06:01:45Z-
dc.date.available2022-04-21T06:01:45Z-
dc.identifierhttp://hdl.handle.net/20.500.11799/104783-
dc.identifier.urihttp://ri.uaemex.mx/handle20.500.11799/104783-
dc.descriptionEn el presente trabajo se describe un procedimiento simple y fácil para la preparación de pirrolidinonas 5-sustituidas a partir de un acoplamiento entre iones N-aciliminio y reactivos organometálicos derivados de zinc-
dc.descriptionA coupling reaction between cyclic N-acyliminium ions with organozinc reagents is described. The cyclic N-acyliminium ions, generated in situ from N-substituted-5-hydroxy-2-pyrrolidinones by treatment with BF3-etherate or titanium tetrachloride, were trapped by the organozinc reagent, formed by the alkylbromide in the presence of zinc in the same reaction media. The N-substituted 5-allyl-2-pyrrolidinones generated using this method, serves as versatile intermediates for the synthesis of azabicyclic systems with indolizidine and pyrroloazepinolizidine cores.-
dc.languageeng-
dc.publisherThieme-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0-
dc.source0039-7881-
dc.subjectSynthesis of 5-Substituted-2-pyrrolidinones by coupling of organozinc reagents with cyclic N-acyliminium ions-
dc.subjectinfo:eu-repo/classification/cti/2-
dc.titleSynthesis of 5-substituted 2-pyrrolidinones by coupling of organozinc reagents with cyclic N-acyliminium ions-
dc.typearticle-
dc.audiencestudents-
dc.audienceresearchers-
item.grantfulltextnone-
item.fulltextNo Fulltext-
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