Please use this identifier to cite or link to this item: http://ri.uaemex.mx/handle20.500.11799/110150
DC FieldValueLanguage
dc.creatorVíctor Sánchez Mendieta-
dc.creatorLuis David Rosales Vázquez-
dc.creatorIVAN JONATHAN BAZANY RODRIGUEZ-
dc.creatorSIMON HERNANDEZ ORTEGA-
dc.creatorALFREDO RAFAEL VILCHIS NESTOR-
dc.creatorJOSE DE JESUS CAZARES MARINERO-
dc.creatorALEJANDRO DORAZCO GONZALEZ-
dc.date2020-04-27-
dc.date.accessioned2022-04-21T06:03:24Z-
dc.date.available2022-04-21T06:03:24Z-
dc.identifierhttp://hdl.handle.net/20.500.11799/110150-
dc.identifier.urihttp://ri.uaemex.mx/handle20.500.11799/110150-
dc.descriptionArticulo de investigación publicado en revista indexada.-
dc.descriptionA new blue photoluminescent 2D metal–organic framework, 1, with formula {[Zn2( 2-BDC)2 (iQ)2]}1 has been synthesized in a high yield under solvothermal conditions by reacting Zn(II) ions with 1,4-benzenedicarboxylic acid (H2BDC) and isoquinoline (iQ) in DMF. Compound 1 was thoroughly characterized by single-crystal X-ray di raction, solid-state cross-polarization magic-angle spinning 13C NMR, X-ray powder di raction, scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), and thermoanalysis. The crystal structure of 1 showed interpenetrated 2D frameworks consisting of dinuclear paddle-wheel cores Zn2; moreover, this material possessed thermostability up to 310 C. The CPMAS 13C-NMR spectrum of 1 is consistent with the symmetry of the crystal structure. Luminescence studies showed that 1 strongly enhances its fluorescence emission in the presence of xylene isomers with a pronounced selectivity to p-xylene.-
dc.descriptionUniversidad Autónoma del Estado de México (Project 4995/2020CIB)-
dc.languageeng-
dc.publisherProf. Dr. Helmut Cölfen-
dc.relation10-
dc.relation2020-
dc.relation10.3390/cryst10050344-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0-
dc.source2073-4352-
dc.subjectxylene isomers-
dc.subjectfluorescent sensing-
dc.subjectMOF-2 derivative-
dc.subjectinfo:eu-repo/classification/cti/2-
dc.titleStructure of a Luminescent MOF-2 Derivative with a Core of Zn(II)-Terephthalate-Isoquinoline and Its Application in Sensing of Xylenes-
dc.typearticle-
dc.audiencestudents-
dc.audienceresearchers-
item.grantfulltextnone-
item.fulltextNo Fulltext-
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