Please use this identifier to cite or link to this item:
http://ri.uaemex.mx/handle20.500.11799/112482| DC Field | Value | Language |
|---|---|---|
| dc.creator | Jonathan Jaramillo Garcia | - |
| dc.creator | RAUL ALBERTO MORALES LUCKIE | - |
| dc.creator | Diego Martínez Otero | - |
| dc.creator | Víctor Sánchez Mendieta | - |
| dc.date | 2021-10-07 | - |
| dc.date.accessioned | 2022-04-28T00:54:35Z | - |
| dc.date.available | 2022-04-28T00:54:35Z | - |
| dc.identifier | http://hdl.handle.net/20.500.11799/112482 | - |
| dc.identifier.uri | http://ri.uaemex.mx/handle20.500.11799/112482 | - |
| dc.description | Influence of the 2D supramolecular array in the distorted trigonal prismatic geometry of a dinuclear Co(II)-muconate complex exhibiting weak antiferromagnetic exchange. | - |
| dc.description | Dinuclear complex [ Co2(H2O)4(dmb)2(muc)][muc] (1) (muc = muconate; dmb = 5,5′-dimethyl-2,2′-bipyridine), was obtained by self-assembly solution reaction, under ambient conditions, and it was structurally characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system in the C2/c space group. Noticeably, the six-coordinated Co(II) centers display a distorted-trigonal prismatic configuration. This uncommon coordination geometry is attained due to the hydrogen bonding interactions of the crystalline structure of 1, yielding thus a 2D supramolecular array. Magnetic properties measurements reveal that metaprism 1 exhibits weak antiferromagnetic ordering with θ(C-W) = -14.4 K and an E2 = 0.032 cm− 1 accordingly to Curie–Weiss model and Rueff phenomenological approach, respectively. | - |
| dc.description | Universidad Autónoma del Estado de México Universidad Nacional Autónoma de México | - |
| dc.language | eng | - |
| dc.publisher | Springer | - |
| dc.relation | no disponible | - |
| dc.relation | 2021 | - |
| dc.relation | no disponible | - |
| dc.relation | 10.1007/s10870-021-00907-z | - |
| dc.rights | info:eu-repo/semantics/openAccess | - |
| dc.rights | http://creativecommons.org/licenses/by-nc-nd/4.0 | - |
| dc.source | 1074-1542 | - |
| dc.subject | Dinuclear Co complex | - |
| dc.subject | Trigonal prismatic | - |
| dc.subject | Metaprism | - |
| dc.subject | Antiferromagnetism | - |
| dc.subject | Muconate | - |
| dc.subject | info:eu-repo/classification/cti/2 | - |
| dc.title | Dinuclear Co(II)‑Muconate Complex Displaying Distorted‑TrigonalPrismatic Geometry, 2D Supramolecular Array and Weak Antiferromagnetism | - |
| dc.type | article | - |
| dc.audience | students | - |
| dc.audience | researchers | - |
| item.grantfulltext | none | - |
| item.fulltext | No Fulltext | - |
| Appears in Collections: | Producción | |
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