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http://ri.uaemex.mx/handle20.500.11799/39320| Title: | Formation of Two 1:1 Chlorogenic Acid: B-cyclodextrin Complexes at pH 5: Spectroscopic, Thermodynamic and Voltammetric study | Keywords: | Química;B-cyclodextrin;chlorogenic acid;inclusion complexes;fluorescence;isothermal titration calorimetry (ITC);thermodynamic parameters;info:eu-repo/classification/cti/2 | Publisher: | Sociedad Química de México | Project: | http://www.redalyc.org/revista.oa?id=475 | Description: | Complexation of chlorogenic acid (CA) by b-cyclodextrin (b-CD) at mildly acidic pH, was studied by fluorescence spectroscopy, isothermal titration calorimetry (ITC), cyclic voltammetry (CV) and NMR spectroscopy. Thermodynamic parameters (DH°, DS° and K) determined by both fluorescence and ITC, showed that the complexation of CA by b-CD is an enthalpy-driven process. Results show that CA molecule can be complexed through both polyphenolic and quinic acid moiety, leading to the formation of two supramolecular isomers with 1,1 stoichiometry. | Other Identifiers: | http://hdl.handle.net/20.500.11799/39320 | Rights: | info:eu-repo/semantics/openAcess info:eu-repo/semantics/Journal of the Mexican Chemical Society info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0 |
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