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Title: | Reduction of trichloromethyl to gem-dichloromethyl group with triphenylphosphine and water in ethyl acetateethyl Compounds Promoted by Triphenylphosphine/water | Keywords: | Research Subject Categories;info:eu-repo/classification/cti/2 | Publisher: | Chemistry Select | Project: | DOI;10.1002/slct.201702003 | Description: | En este trabajo se reporta un método de reducción de triclorometil compuestos bajo condiciones amigables al medio ambiente. A novel and efficient way of reducing trichloromethyl to gem-dichloromethyl compounds using environmentally friendly conditions has been developed. This reduction process consists of the treatment of a trichloromethyl compound with water and triphenylphosphine using ethyl acetate as solvent. This reaction proceeds in good yield when a strong electron-withdrawing group is attached to the trichloromethyl derivative. Conacyt |
URI: | http://ri.uaemex.mx/handle20.500.11799/67758 | Other Identifiers: | http://hdl.handle.net/20.500.11799/67758 | Rights: | info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0 |
Appears in Collections: | Producción |
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