Strong Ferromagnetic Exchange Coupling Mediated by a Bridging Tetrazine Radical in a Dinuclear Nickel Complex.

Please use this identifier to cite or link to this item: http://ri.uaemex.mx/handle20.500.11799/68595

Title:	Strong Ferromagnetic Exchange Coupling Mediated by a Bridging Tetrazine Radical in a Dinuclear Nickel Complex.
Keywords:	Bridging Tetrazine;Dinuclear Nickel Complex;Ferromagnetic;info:eu-repo/classification/cti/2
Publisher:	Inorganic Chemistry
Description:	The radical bridged compound [(Ni- (TPMA))2-μ-bmtz•−](BF4)3·3CH3CN (bmtz = 3,6-bis- (2′-pyrimidyl)-1,2,4,5-tetrazine, TPMA = tris(2- pyridylmethyl)amine) exhibits strong ferromagnetic exchange between the S = 1 NiII centers and the bridging S = 1/2 bmtz radical with J = 96 ± 5 cm−1 (−2JNi‑radSNiSrad). DFT calculations support the existence of strong ferromagnetic exchange. Department of Energy Office of Science Graduate Fellowship, Instituto de Ciencia y Tecnología del Distrito Federal (ICyTDF) National Science Foundation (CHE-1310574) and the Robert A. Welch Foundation (A-1449).
URI:	http://ri.uaemex.mx/handle20.500.11799/68595
Other Identifiers:	http://hdl.handle.net/20.500.11799/68595
Rights:	info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0
Appears in Collections:	Producción

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