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Please use this identifier to cite or link to this item: http://ri.uaemex.mx/handle20.500.11799/68647
DC FieldValueLanguage
dc.creatorXuan Zhang-
dc.creatorHaomiao Xie-
dc.creatorMARIA FERNANDA BALLESTEROS RIVAS-
dc.creatorZhao-xi Wang-
dc.creatorKim Renee Dunbar-
dc.date2015-08-13-
dc.date.accessioned2022-04-21T05:16:47Z-
dc.date.available2022-04-21T05:16:47Z-
dc.identifierhttp://hdl.handle.net/20.500.11799/68647-
dc.identifier.urihttp://ri.uaemex.mx/handle20.500.11799/68647-
dc.descriptionThe incorporation of TCNQ˙− (7,7,8,8-tetracyanoquinodimethane) radicals as counterions for the spin-crossover material [Co(pyterpy)2](TCNQ)2·solvent (pyterpy = 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine) leads to structural distortions of the [Co(pyterpy)2]2+ spin-crossover cation as compared to [Co(pyterpy)2](PF6)2. Variable temperature structural and magnetic studies indicate that the supramolecular π-stacking interactions between the terminal pyridyl groups and TCNQ radicals play a crucial role in the spin-crossover properties.-
dc.languageeng-
dc.publisherroyal chemical society-
dc.relation3, 9292-9298;-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0-
dc.source2050-7526-
dc.subjectsupramoleculares-
dc.subjectgrupos piridilo terminales-
dc.subjectdistorsiones estructurales-
dc.subjectspin-crossover-
dc.subjectinfo:eu-repo/classification/cti/2-
dc.titleStructural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions.-
dc.typearticle-
dc.audiencestudents-
dc.audienceresearchers-
item.fulltextNo Fulltext-
item.grantfulltextnone-
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