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http://ri.uaemex.mx/handle20.500.11799/68647| Title: | Structural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions. | Keywords: | supramoleculares;grupos piridilo terminales;distorsiones estructurales;spin-crossover;info:eu-repo/classification/cti/2 | Publisher: | royal chemical society | Project: | 3, 9292-9298; | Description: | The incorporation of TCNQ˙− (7,7,8,8-tetracyanoquinodimethane) radicals as counterions for the spin-crossover material [Co(pyterpy)2](TCNQ)2·solvent (pyterpy = 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine) leads to structural distortions of the [Co(pyterpy)2]2+ spin-crossover cation as compared to [Co(pyterpy)2](PF6)2. Variable temperature structural and magnetic studies indicate that the supramolecular π-stacking interactions between the terminal pyridyl groups and TCNQ radicals play a crucial role in the spin-crossover properties. | URI: | http://ri.uaemex.mx/handle20.500.11799/68647 | Other Identifiers: | http://hdl.handle.net/20.500.11799/68647 | Rights: | info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/4.0 |
| Appears in Collections: | Producción |
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