Potentially Toxic Elements in Terrestrial Mosses in the Vicinity of a Stibnite Mine in Pinal de Amoles, Mexico

Abstract

Mining waste often contains elevated concentrations of V, Cr, As, Sb, and Pb. Stibnite mining, during extraction and processing, generates waste that is deposited directly onto soil without vegetation cover, potentially leading to environmental pollution. This study assessed concentrations of potentially toxic elements (PTEs) in the rhizoids and stems-phyllidia of terrestrial mosses near antimony mines and used these mosses as biomonitors of soil contamination. Results obtained via energy-dispersive X-ray fluorescence spectrometry showed the highest concentrations of As, Sb, and Pb in mosses growing on mining rubble, reflecting elevated contaminant levels in the study area. Concentrations of As, Sb, and Pb differed significantly between mosses from mine rubble sites and those from forest and meander sites. Both rhizoids and stems/phyllidia of mosses from rubble sites showed high enrichment factors (EFs) for As, Sb, and Pb. Notably, PTEs concentrations in mosses from the forest area were lower than values reported for other regions, whereas concentrations in the mine rubble area exceeded those reported for other mining-polluted regions worldwide.