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dc.contributor.author	DE LA CRUZ CORDERO, RICARDO ABRAHAM
dc.contributor.author	LABASTIDA GALVAN, VICTORIA
dc.contributor.author	FERNANDEZ ZERTUCHE, MARIO
dc.contributor.author	ORDOÑEZ PALACIOS, JOSE MARIO
dc.creator	DE LA CRUZ CORDERO, RICARDO ABRAHAM; 121952
dc.creator	LABASTIDA GALVAN, VICTORIA; 509032
dc.creator	FERNANDEZ ZERTUCHE, MARIO; 15480
dc.creator	ORDOÑEZ PALACIOS, JOSE MARIO; 16485
dc.date.accessioned	2016-03-16T17:17:29Z
dc.date.available	2016-03-16T17:17:29Z
dc.date.issued	2005
dc.identifier	http://www.redalyc.org/articulo.oa?id=47549404
dc.identifier.uri	http://hdl.handle.net/20.500.11799/39328
dc.description	Reduction of (3S)-N,N-dibenzylamino-2-ketophosphonates 9a-d derived from L-amino acids was carried out with catecholborane at -20 oC to afford the (3S)-N,N-dibenzylamino-(2R)-hydroxy-phosphonates syn-10a-d, whereas the reduction of (3S)-N-benzylamino-2- ketophosphonates 13a-d with Zn(BH4)2 at -78 oC yield (3S)-N-benzylamino-( 2S)-hydroxyphosphonates anti-14a-d. The reduction in both cases was in good chemical yields and with high diastereoselectivity. The hydrolysis and hydrogenolysis of 10a-d and 14a-d afford the (3S)-amino-(2R)-hydroxyphosphonic acids 6 and (3S)-amino-(2S)- hydroxyphosphonic acids 7, respectively, which are analogues of phosphostatine.
dc.format	application/pdf
dc.language.iso	eng	es
dc.publisher	Sociedad Química de México
dc.relation	http://www.redalyc.org/revista.oa?id=475
dc.rights	openAccess	es
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0
dc.source	Journal of the Mexican Chemical Society (México) Num.4 Vol.49
dc.subject	Química	es
dc.subject	Phosphostatine	es
dc.subject	aminophosphonic acids	es
dc.subject	β-ketophosphonates,	es
dc.subject	diastereoselective reduction	es
dc.subject.classification	BIOLOGÍA Y QUÍMICA
dc.title	Preparation of Phosphostatine Analogues From L-amino acids	es
dc.type	Artículo	es
dc.provenance	Científica	es
dc.road	Dorada	es
dc.ambito	Internacional	es
dc.audience	students	es
dc.audience	researchers	es
dc.type.conacyt	article
dc.identificator	2

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