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dc.contributor.author | VIGUERAS SANTIAGO, ENRIQUE | |
dc.contributor.author | HERNANDEZ LOPEZ, SUSANA | |
dc.contributor.author | RODRIGUEZ ROMERO, ADELA | |
dc.creator | VIGUERAS SANTIAGO, ENRIQUE; 25387 | |
dc.creator | HERNANDEZ LOPEZ, SUSANA; 30493 | |
dc.creator | RODRIGUEZ ROMERO, ADELA; 5435 | |
dc.date.accessioned | 2016-03-16T17:19:19Z | |
dc.date.available | 2016-03-16T17:19:19Z | |
dc.date.issued | 2006 | |
dc.identifier | http://www.redalyc.org/articulo.oa?id=94219101 | |
dc.identifier.uri | http://hdl.handle.net/20.500.11799/39988 | |
dc.description | Photochemical cross-linking studies at different temperatures (room temperature, Tg and maximum exothermal of crosslinking peak) are shown for three series of polymers containing diacetylene-groups in the main chain and polar chromophores derived from benzene, azo- and di-azobenzene, as pendant groups. We establish the optimal irradiation time and temperature that permit them being poled and cross-linked with minimal dye-degradation. The degradation process was followed by a diminution of the respective maximum absorption peak. These conditions could extend the mean life-time of the second order nonlinear optical properties, studied previously. Photochemical cross-linking at each polymer´s Tg (50-130°C) was the most convenient process. It took less than 10 min and was monitored by IR spectroscopy | |
dc.format | application/pdf | |
dc.language.iso | eng | es |
dc.publisher | Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C. | |
dc.relation | http://www.redalyc.org/revista.oa?id=942 | |
dc.rights | Superficies y vacío | |
dc.rights | openAccess | es |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0 | |
dc.source | Superficies y vacío (México) Num.1 Vol.19 | |
dc.subject | Física, Astronomía y Matemáticas | es |
dc.subject | Diacetylene Cross-linking Photodegradation | es |
dc.subject.classification | CIENCIAS FÍSICO MATEMÁTICAS Y CIENCIAS DE LA TIERRA | |
dc.title | Photochemical cross-linking study of polymers containing diacetylene groups in their main chain and azobenzene compounds as pendant groups | es |
dc.type | Artículo | es |
dc.provenance | Científica | es |
dc.road | Dorada | es |
dc.ambito | Internacional | es |
dc.audience | students | es |
dc.audience | researchers | es |
dc.type.conacyt | article | |
dc.identificator | 1 |
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