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dc.contributor.author JARAMILLO GARCIA, JONATHAN
dc.contributor.author TELLEZ LOPEZ, ANTONIO
dc.contributor.author MARTINEZ DOMINGUEZ, ROGELIO
dc.contributor.author MORALES LUCKIE, RAUL ALBERTO
dc.contributor.author MARTINEZ OTERO, DIEGO
dc.contributor.author SANCHEZ MENDIETA, VICTOR
dc.contributor.author ESCUDERO DERAT, ROBERTO
dc.creator JARAMILLO GARCIA, JONATHAN; 701384
dc.creator TELLEZ LOPEZ, ANTONIO; 701362
dc.creator MARTINEZ DOMINGUEZ, ROGELIO; 784957
dc.creator MORALES LUCKIE, RAUL ALBERTO; 45308
dc.creator MARTINEZ OTERO, DIEGO; 176977
dc.creator SANCHEZ MENDIETA, VICTOR; 13230
dc.creator ESCUDERO DERAT, ROBERTO; 3287
dc.date.accessioned 2017-03-13T18:26:56Z
dc.date.available 2017-03-13T18:26:56Z
dc.date.issued 2016-05-04
dc.identifier.issn 0095-8972
dc.identifier.uri http://hdl.handle.net/20.500.11799/65835
dc.description.abstract Abstract Manganese coordination polymers {Mn(- fum)(5dmb)(H2O)2}n (1) and {[Mn2(fum)2(4dmb)2] H2O}n (2) (fum= fumarato; 5dmb = 5,50-dimethyl-2,20-bipyridine; 4dmb = 4,40-dimethyl-2,20-bipyridine) were obtained from one-pot, solution reactions under ambient conditions. The fum ligand acquires different coordination modes in the presence of the different dmb ancillary ligands, promoting distinctive crystal structures, including divergent dimensionalities. Thus, X-ray single-crystal data reveal that complex 1 crystallizes in a monoclinic system with C2/c space group and forms an infinite one-dimensional polymer. The Mn(II) center is six-coordinated and displays a distorted octahedral configuration. In addition, the solid-state selfassembly of the polymeric structure of 1 gives rise to a twodimensional (2D) supramolecular framework, mainly through hydrogen bonding. In contrast, complex 2 crystallizes in a monoclinic system with a Cc space group and forms an infinite 2D coordination polymer having dinuclear units. The Mn(II) center has a distorted octahedral configuration. The thermal stabilities of both coordination polymers were investigated. Variable-temperature magnetic measurements show that complex 1 is paramagnetic, while complex 2 exhibits weak antiferromagnetic coupling between adjacent Mn(II) centers. es
dc.description.sponsorship supported by CONACyT project 129293, DGAPA-UNAM project IN106014, and ICYTDF, project PICCO. es
dc.language.iso eng es
dc.publisher Tylor and francis es
dc.rights openAccess es
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0
dc.subject research subject categories es
dc.subject.classification BIOLOGÍA Y QUÍMICA
dc.title 1D and 3D supramolecular structures exhibiting weak ferromagnetism in three Cu(II) complexes based on malonato and di-alkyl-2,2’-bipyridines es
dc.type Artículo es
dc.provenance Científica es
dc.road Dorada es
dc.organismo Química es
dc.ambito Estatal es
dc.cve.CenCos 20401 es
dc.cve.progEstudios 631 es
dc.audience students
dc.audience researchers
dc.type.conacyt article
dc.identificator 2


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  • Título
  • 1D and 3D supramolecular structures exhibiting weak ferromagnetism in three Cu(II) complexes based on malonato and di-alkyl-2,2’-bipyridines
  • Autor
  • JARAMILLO GARCIA, JONATHAN
  • TELLEZ LOPEZ, ANTONIO
  • MARTINEZ DOMINGUEZ, ROGELIO
  • MORALES LUCKIE, RAUL ALBERTO
  • MARTINEZ OTERO, DIEGO
  • SANCHEZ MENDIETA, VICTOR
  • ESCUDERO DERAT, ROBERTO
  • Fecha de publicación
  • 2016-05-04
  • Editor
  • Tylor and francis
  • Tipo de documento
  • Artículo
  • Palabras clave
  • research subject categories
  • Los documentos depositados en el Repositorio Institucional de la Universidad Autónoma del Estado de México se encuentran a disposición en Acceso Abierto bajo la licencia Creative Commons: Atribución-NoComercial-SinDerivar 4.0 Internacional (CC BY-NC-ND 4.0)

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