Structural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions.

Zhang, Xuan; Xie, Haomiao; BALLESTEROS RIVAS, MARIA FERNANDA; Wang, Zhao-xi; Dunbar, Kim Renee

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dc.contributor.author	Zhang, Xuan
dc.contributor.author	Xie, Haomiao
dc.contributor.author	BALLESTEROS RIVAS, MARIA FERNANDA
dc.contributor.author	Wang, Zhao-xi
dc.contributor.author	Dunbar, Kim Renee
dc.creator	Zhang, Xuan;#0000-0001-5684-3064
dc.creator	Xie, Haomiao;#0000-0001-7688-6571
dc.creator	BALLESTEROS RIVAS, MARIA FERNANDA; 177336
dc.creator	Wang, Zhao-xi;#0000-0003-4644-7935
dc.creator	Dunbar, Kim Renee;#0000-0001-7170-3908
dc.date.accessioned	2018-02-16T20:12:22Z
dc.date.available	2018-02-16T20:12:22Z
dc.date.issued	2015-08-13
dc.identifier.issn	2050-7526
dc.identifier.uri	http://hdl.handle.net/20.500.11799/68647
dc.description.abstract	The incorporation of TCNQ˙− (7,7,8,8-tetracyanoquinodimethane) radicals as counterions for the spin-crossover material [Co(pyterpy)2](TCNQ)2·solvent (pyterpy = 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine) leads to structural distortions of the [Co(pyterpy)2]2+ spin-crossover cation as compared to [Co(pyterpy)2](PF6)2. Variable temperature structural and magnetic studies indicate that the supramolecular π-stacking interactions between the terminal pyridyl groups and TCNQ radicals play a crucial role in the spin-crossover properties.	es
dc.language.iso	eng	es
dc.publisher	royal chemical society	es
dc.relation.ispartofseries	3, 9292-9298;
dc.rights	openAccess	es
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0
dc.subject	supramoleculares	es
dc.subject	grupos piridilo terminales	es
dc.subject	distorsiones estructurales	es
dc.subject	spin-crossover	es
dc.subject.classification	BIOLOGÍA Y QUÍMICA
dc.title	Structural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions.	es
dc.type	Artículo	es
dc.provenance	Científica	es
dc.road	Dorada	es
dc.ambito	Nacional	es
dc.audience	students	es
dc.audience	researchers	es
dc.type.conacyt	article
dc.identificator	2

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Título
Structural distortions of the spin-crossover material [Co(pyterpy)2](TCNQ)2 mediated by supramolecular interactions.
Autor
Zhang, Xuan
Xie, Haomiao
BALLESTEROS RIVAS, MARIA FERNANDA
Wang, Zhao-xi
Dunbar, Kim Renee
Fecha de publicación
2015-08-13
Editor
royal chemical society
Tipo de documento
Artículo
Palabras clave
supramoleculares
grupos piridilo terminales
distorsiones estructurales
spin-crossover